Chemische Berichte

Notizen/Notes Synthesis of β??Oxo Esters from Silyl Enol Ethers and Dichlorobis (phenoxy) methane

H Mayr, A Cambanis, E Bäuml

文献索引：Cambanis, Anton; Baeuml, Englbert; Mayr, Herbert Synthesis, 1988 , # 12 p. 961

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被引用次数: 1

摘要

Bis (ary1oxy) dichloromethanes (eg 1) are readily available by radical-induced chlorination of formaldehyde diary1 acetals'). Like 2, 2-dichloro-1, 3-benzodioxol, which is used for the electrophilic carboxylation of aromatic compounds*) and of alkenes3), they represent R02C@ equivalents and have been employed for the synthesis of P, y-unsaturated esters from allyl~ ilanes~). In this paper we report on the reaction of bis (ary1oxy) ...