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Selective reduction of imonium salts by sodium hydrogen telluride

DHR Barton, A Fekih, X Lusinchi

文献索引:Barton, Derek H. R.; Fekih, Abdelwaheb; Lusinchi, Xavier Tetrahedron Letters, 1985 , vol. 26, # 31 p. 3693 - 3696

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被引用次数: 24

摘要

Abstract Sodium hydrogen telluride reduces imonium salts effeciently at room temperature in ethanol. The products of the reaction depend upon the pH. Under alkaline pH only dihydro- derivatives are formed. Under acid pH (6-7) the products depend on the structure of the salt. The tellurium con be recovered quantitatively.