Tetrahedron letters

Preparation of 1-alkynyl 2-(trimethylsilyl) ethyl sulfides as thiolate anion precursors for self-assembled monolayers

…, S Shimada, S Ohnishi, F Nakanishi, H Matsuda

文献索引：Takeda, Hiroyuki; Shimada, Satoru; Ohnishi, Satomi; Nakanishi, Fusae; Matsuda, Hiro Tetrahedron Letters, 1998 , vol. 39, # 22 p. 3701 - 3704

全文：HTML全文

被引用次数: 32

摘要

Syntheses of 1-alkynyl 2-(trimethylsilyl) ethyl sulfides are reported. Deprotection of 2- (trimethylsilyl) ethyl groups using fluoride ions permits the formation of thiolate anions which are trapped by in situ alkylation with methyl iodide and can be used to produce self- assembled monolayers on gold.