Energetic constraints in the 218 nm photolysis of acetic acid

SS Hunnicutt, LD Waits, JA Guest

文献索引：Hunnicutt, Sally S.; Waits, Leslie D.; Guest, Joyce A. Journal of Physical Chemistry, 1989 , vol. 93, # 13 p. 5188 - 5195

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被引用次数: 54

摘要

Acetic acid has been photolyzed at 218 nm under both room temperature and jet-cooled conditions. The nascent OH X2II (v"= O) photofragment has been probed by use of laser fluorescence excitation to determine its scalar and vector quantities. Jet-cooled acetic acid leads to OH photofragments with about 30% less rotational excitation than does the room temperature acetic acid. In both cases, only a few percent of the total available energy is ...