The entropy inhibition of a gas-phase SN 2 reaction
S Okada, Y Abe, S Taniguchi, S Yamabe
文献索引：Okada, Satoshi; Abe, Yasuo; Taniguchi, Setsuo; Yamabe, Shinichi Journal of the Chemical Society, Chemical Communications, 1989 , # 10 p. 610 - 612
The recent development of ion cyclotron resonance and high pressure mass spectrometry makes the measurement of gas-phase sN2 reactions feasible. The SN2 reaction involving positive ions is of particular mechanistic interest. The combi- nation of methanol and protonated methanol has been reported to proceed via the typical sN2 mechanism with Walden inversion.' In the present work, the kinetics of a gas-phase reaction between protonated methanol and ammonia ...
