Five-co-ordination with 'hybrid'ligands. Part VI. Cobalt (II) and nickel (II) complexes with a quadridentate tripod ligand having a NOPP donor set

R Morassi, L Sacconi

文献索引：Morassi,R.; Sacconi,L. Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1971 , p. 492 - 499

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被引用次数: 34

摘要

The quadridentate 'tripod'ligand-bis-(2-diphenylphosphinoethyl)-2-methoxyethylamine (NOP donor set) forms cobalt () and nickel () complexes with the general formulae [MLX] Y (X= Cl, Br, I, NCS; Y= Br, I, PF, BPh),[CoLX][CoX](X= Br, I), and CoLX (X= Cl, Br, I, NCS). The complex cations [NiLX] are low-spin with an