Journal of the American Chemical Society

Reactions of a graded set of radicals with N-bromosuccinimide; two transition states

RL Tlumak, PS Skell

文献索引：Tlumak, Robert L.; Skell Philip S. Journal of the American Chemical Society, 1982 , vol. 104, # 25 p. 7267 - 7274

全文：HTML全文

被引用次数: 21

摘要

Abstract: The reactions of N-bromosuccinimide with a series of radicals have been studied. These reactions fall into two categories, the more reactive radicals producing a-succinimidyl and the less reactive radicals producing r-succinimidyl. The threshold for the changeover from one reaction domain to the other occurs with radicals less reactive than secondary alkyls. These results are interpreted with two transition states, an in-line transition state for ...