Study of the reaction chlorine monoxide+ methyl peroxide. fwdarw. products at 300 K

…, JP Burrows, W Schneider, GK Moortgat…

文献索引：Simon, F. G.; Burrows, J. P.; Schneider, W.; Moortgat, G. K.; Crutzen, P. J. Journal of Physical Chemistry, 1989 , vol. 93, # 23 p. 7807 - 7813

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被引用次数: 32

摘要

The first experimental study of the reaction CIO+ CH302-+ products (1) is reported. The rate coefficient kl and the product distributions were investigated in the modulated photolysis of CI2/CH4/CI, O/O2 mixtures. Reactants and products have been monitored by using UV-vis and Fourier-transform infrared gas-phase absorption spectroscopies. The value of k, was found to be equal to (3.1 i 1.7) X cm3 molecule-'sI at 300 K and 240 Torr total pressure. ...