Chemosphere

Identification of organic peroxides in the oxidation of c 1 c 3 alkanes

B Qi, YH Zhang, ZM Chen, KS Shao, XY Tang, M Hu

文献索引：Qi; Zhang; Chen; Shao; Tang; Hu Chemosphere, 1999 , vol. 38, # 6 p. 1213 - 1221

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被引用次数: 12

摘要

Formation of organic peroxides in oxidation of C1 C3 alkanes initiated by Cl atoms in O2 N2 mixtures at 760 torr and 298 K was studied with FT-IR and HPLC method in laboratory. Methyl hydroperoxide (MHP) and ethyl hydroperoxide (EHP) were the main peroxide products and formed early in the oxidation process. Hydroxymethyl hydroperoxide (HOCH2OOH, HMHP) was identified in the reaction systems. Other two types of peroxides ...