Tetrahedron letters

tert-Butylmethoxyphenylsilyl ether-a new selective, stable alcohol protecting group with remarkable lability to fluoride.

Y Guindon, R Fortin, C Yoakim, JW Gillard

文献索引：Guindon, Yvan; Fortin, Rejean; Yoakim, Christiane; Gillard, John W. Tetrahedron Letters, 1984 , vol. 25, # 42 p. 4717 - 4720

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被引用次数: 30

摘要

This document does not have an outline. ... JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. ... Author links open the overlay panel. Numbers correspond to the affiliation list which can be exposed by using the show more link. ... Secondary alcohols react very slowly (T 1/2 > 24 hrs) with our reagent in CH 2 Cl 2 . Addition to the reaction mixture of .02 equiv. of DMF accelerates the reaction significantly (T 1/2 = 90 min).

~80%

~65%

94124-39-7

叔丁基甲氧苯基溴硅烷

~86%

Stereoselective total synthesis of crucigasterins A, B and D...

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Dimethylboron bromide and diphenylboron bromide: cleavage of...

[Guindon, Yvan; Yoakim, Christiane; Morton, Howard E. Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 3912 - 3920]

Selective deprotection of t-butyldiphenylsilyl ethers in the...

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Dimethylboron bromide and diphenylboron bromide: cleavage of...

[Guindon, Yvan; Yoakim, Christiane; Morton, Howard E. Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 3912 - 3920]

Symmetrical alkoxysilyl ethers. A new class of alcohol-prote...

[Gillard, John W.; Fortin, Rejean; Morton, Howard E.; Yoakim, Christiane; Quesnelle, Claude A.; at al. Journal of Organic Chemistry, 1988 , vol. 53, # 11 p. 2602 - 2608]