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Polar Effects of Substitutents on the Reaction Rates of 4-R-and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene

W Greizerstein, RA Bonelli…

文献索引:Greizerstein,W. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 1026 - 1032

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被引用次数: 36

摘要

The nucleophilic substitutioii of lialogeii ill. I-lC-2-iiitrohalogenobeiizeiies has been studied q~ iaiititatively by Berliner and A210iiackLo in the solvolysis of 4-R-2-nitrobroinobeiizeiies in piperidine; by Miller and coworkers, l 1 by Bunnett and coworkers'? and by Eliel and Nelson13 in the reactions of 4-It-2-nitrochlorobenzenes with sodiuiii methoxide iii methanol. Bunnett and Snipes14 studied the