The Stereochemical Course of Substitution Reactions at Halomethylphosphonates

CR Hall, TD Inch, NE Williams

文献索引：Hall, C. Richard; Inch, Thomas D.; Williams, Nancy E. Phosphorus and Sulfur and the Related Elements, 1983 , vol. 18, p. 213 - 216

全文：HTML全文

被引用次数: 0

摘要

Abstract The stereochemistry of substitution at dihalomethylphosphonothioates is the same as for phosphogothioates whereas that for monohalomethylphosphono- thioates is similar to the unsubstituted phosphoflothioates. ... It has been suggested' that halomethylphosphonates are electronically better analogues of natural phosphates than the corresponding unsubstituted phosphonates and may therefore be useful in studies of biosynthetic pathways and enzyme ...