Radical allylations by reaction of azides with allylindium dichloride

…, M Minozzi, D Nanni, P Spagnolo, G Zanardi

文献索引：Bencivenni, Giorgio; Lanza, Tommaso; Minozzi, Matteo; Nanni, Daniele; Spagnolo, Piero; Zanardi, Giuseppe Organic and Biomolecular Chemistry, 2010 , vol. 8, # 15 p. 3444 - 3450

全文：HTML全文

被引用次数: 10

摘要

Allylindium dichloride is an effective reagent for carrying out photolytically initiated radical allylation reactions, as also proved by EPR experiments. In the presence of suitable azides that can give rise to electrophilic radicals, a homolytic chain reaction occurs with formation of allylated compounds. With δ-azido esters and chlorides generation of primary indiumaminyl radicals is followed by a very efficient 1, 5-H shift process that gives rise to electrophilic ...