The Journal of Organic Chemistry

An efficient synthesis of N-bromoperhalo-1-alkanimines

BA O'Brien, DD DesMarteau

文献索引：O'Brien, Brian A.; DesMarteau, Darryl D. Journal of Organic Chemistry, 1984 , vol. 49, # 8 p. 1467 - 1469

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被引用次数: 18

摘要

Summary: Certain perhalogenated nitriles have been found to react readily with bromine and active cesium fluoride to afford high yields of N-bromoperhalo-l-alkanimines (€ &FC= NBr;€ &= CF,, C2F5, n-C3F,, CF, Cl, CCl,). Photolysis of the perfluorinated N-bromo compounds af-fords the novel perfluoroazines RfFC= NN= CFRp