Journal of the American Chemical Society

Anthracycline synthesis with Fischer carbene complexes

WD Wulff, PC Tang

文献索引：Wulff, William D.; Tang, Peng-Cho Journal of the American Chemical Society, 1984 , vol. 106, # 2 p. 434 - 436

全文：HTML全文

被引用次数: 55

摘要

0 OH thracyclines involving the benzannulation reaction of chromium carbene complexes and acetylenes. This novel and intriguing reaction was first reported by Dotz, 6 and recently we have examined the scope of the reactions of a $-unsaturated complexes such as la. 7 The particular approach utilizing this benzannulation that is indicated in Scheme I has the potential to solve the three major synthetic problems associated with this family of natural ...