Chemistry letters

Activation of Sn-Se bond: Regioselective ring opening reaction of epoxides with tributylstannyl phenylselenolate in the presence of a Lewis acid

Y Nishiyama, H Ohashi, K Itoh, N Sonoda

文献索引：Nishiyama, Yutaka; Ohashi, Hironori; Itoh, Kazuyoshi; Sonoda, Noboru Chemistry Letters, 1998 , # 2 p. 159 - 160

全文：HTML全文

被引用次数: 22

摘要

抄録 When tributylstannyl phenylselenolate (Bu< SUB> 3 SnSePh) was allowed to react with epoxides in the presence of BF< SUB> 3· OEt< SUB> 2 as a Lewis acid, the ring opening reaction of epoxides proceeded with complete regioselectivity to afford the β-hydroxy phenylselenides in moderate to good yields.