Masked imidazolyl-dipyrromethanes in the synthesis of imidazole-substituted porphyrins

…, KE Borbas, M Taniguchi, JS Lindsey

文献索引：Bhaumik, Jayeeta; Yao, Zhen; Borbas, K. Eszter; Taniguchi, Masahiko; Lindsey, Jonathan S. Journal of Organic Chemistry, 2006 , vol. 71, # 23 p. 8807 - 8817

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被引用次数: 37

摘要

Imidazole-substituted metalloporphyrins are valuable for studies of self-assembly and for applications where water solubility is required. Rational syntheses of porphyrins bearing one or two imidazol-2-yl or imidazol-4-yl groups at the meso positions have been developed. The syntheses employ dipyrromethanes, 1-acyldipyrromethanes, and 1, 9- diacyldipyrromethanes bearing an imidazole group at the 5-position. The polar, reactive ...