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Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron (III) complexes with µ-alkoxo bridges†

S Nishino, H Hosomi, S Ohba, H Matsushima…

文献索引:Nishino, Satoshi; Hosomi, Hiroyuki; Ohba, Shigeru; Matsushima, Hideaki; Tokii, Tadashi; Nishida, Yuzo Journal of the Chemical Society - Dalton Transactions, 1999 , # 9 p. 1509 - 1513

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被引用次数: 20

摘要

Several dinuclear iron () complexes with µ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear-alkanes, such as-nonane and-octane, were used instead of cyclohexane. A mechanism for selective formation of t