Tetrahedron

Structural features controlling cation-radical line-broadening in the 1H-NMR spectra of phenol derivatives in acid media

IKL Al-Khayat, FM Dean, RS Varma

文献索引：Al-Khayat, Isam K. L.; Dean, Francis M.; Varma, Rajender S. Tetrahedron, 1987 , vol. 43, # 20 p. 4649 - 4662

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被引用次数: 1

摘要

The hexachloroantimonates of cation radicals from 2, 3, 4, 7-8, 9-hexahydro-2, 2, 5.7, 7, 10- hexamethylbenzo [1, 2-b; 4, 5-b'] dipyran (1) and the isomeric benzo [1, 2-b; 4, 3-b'] dipyran (3) have been characterised. The production of cation radical from (1) in acid media is limited by acid concentration for weak acids and also by the presence of oxygen for strong acids. The cation radical species (Ar+) is considered to originate from substrate (Ar) via ...