The preparation and characterization of radical cation salts derived from perfluorobenzene, perfluorotoluene, and perfluoronaphthalene

TJ Richardson, FL Tanzella…

文献索引：Richardson, T. J.; Tanzella, F. L.; Bartlett, Neil Journal of the American Chemical Society, 1986 , vol. 108, # 16 p. 4937 - 4943

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被引用次数: 44

摘要

Abstract: The salts C6F6+ AsF6-(yellow), C6F5CF3+ AsF6-(lime green), and CloF8+ AsF6- (dark green) may be prepared by electron oxidation of the appropriate perfluoro aromatic molecule with O2+ AsF6-. Other 02+ salts can be similarly employed as can the more strongly oxidizing transitionmetal hexafluorides, but salts of the latter are more labile than their AsF6-relatives. C6F6+ AsF6-is a convenient electron oxidizer (C6F6AsF6+ CloF8- ...