Thiol peroxidase activity of diorganyl tellurides

…, D Stern, M Pelcman, CM Andersson

文献索引：Engman, Lars; Stern, David; Pelcman, Mikael; Andersson, Carl M. Journal of Organic Chemistry, 1994 , vol. 59, # 8 p. 1973 - 1979

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被引用次数: 106

摘要

A number of diorganyl tellurides, including diary1 tellurides, diheteroaryl tellurides, and alkyl aryl and dialkyl tellurides, were found to catalyze the reaction of hydrogen peroxide with thiols. The thiol peroxidase activity of the compounds was assessed by using a lH NMR method previously developed in our laboratories. In this assay, thiols (N-acetylcysteine, tert- butyl mercaptan, and 1-octyl mercaptan) were oxidized in the presence of hydrogen ...