The Journal of Organic Chemistry

Synthesis of substituted 1, 8-diphenylnaphthalenes

HO House, RW Bashe

文献索引：House,H.O.; Bashe,R.W. Journal of Organic Chemistry, 1967 , vol. 32, p. 784 - 791

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被引用次数: 23

摘要

The initial conjugate addition of the organometallic reagent5 to the octalone (1) yielded, after chromatography, a mixture from which two crystalline stereoisomers of ketone 2 were isolated. The major product, stereoisomer 2a> was not epimerized by treatment with methanolic sodium methoxide and was catalytically hydrogenolyzed to yield the known phenyl ketone (7). 28 Both these observations and analogy with the previously studied ...