A Novel Synthesis of Alkyl, Aryl, Alkenyl, and Alkynyl 1, 6-Diketones

AR Katritzky, Z Huang, Y Fang…

文献索引：Katritzky, Alan R.; Huang, Zhizhen; Fang, Yunfeng; Prakash, Indra Journal of Organic Chemistry, 1999 , vol. 64, # 6 p. 2124 - 2126

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被引用次数: 11

摘要

1, 6-Diketones are somewhat more difficult to synthesize than other types of diketones. 1 Some symmetrical alkyl 1, 6-diketones have been synthesized via bimolecular reduction of alkyl vinyl ketones using sodium or magnesium. 2 Both alkyl and aryl symmetrical 1, 6- diketones are obtained by reacting cadmium alkyls with adipoyl chloride. 3 Siloxycyclopropanes, 4 1, 2-diacylcyclobutanes, 5 and the coupling of vinyl Grignards6 ...