Tetrahedron letters

The PdCl 2/R 3 SiH system for the silylation of nucleosides

C Ferreri, C Costantino, R Romeo, C Chatgilialoglu

文献索引：Ferreri; Costantino; Romeo; Chatgilialoglu Tetrahedron Letters, 1999 , vol. 40, # 6 p. 1197 - 1200

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被引用次数: 12

摘要

Convenient syntheses of TIPDS-Cl 2 and TBDMS-Br from the corresponding hydrides were obtained by using catalytic PdCl 2 and CCl 4 or CH 2 Br 2 , respectively. These systems can be successfully applied in tandem procedures for improved silylation of nucleosides. ... Convenient syntheses of TIPDS-Cl 2 and TBDMS-Br from the corresponding silicon hydrides have been obtained. One-pot nucleoside silylations by using silicon hydrides have also been carried out.