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Journal of Organometallic Chemistry

Synthesis of organotrialkylstannanes. The reaction between organic halides and hexaalkyldistannanes in the presence of palladium complexes

H Azizian, C Eaborn, A Pidcock

文献索引:Azizian, Hormoz; Eaborn, Colin; Pidcock, Alan Journal of Organometallic Chemistry, 1981 , vol. 215, # 1 p. 49 - 58

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被引用次数: 183

摘要

Abstract The aryl halides YC 6 H 4 X (X= Br or I) have been shown to react with the distannanes (R 3 Sn) 2 (R= n-Bu or Me) in toluene in the presence of [Pd (PPh 3) 4] or [PdBr 2 (PPh 3) 2] to give the compounds YC 6 H 4 SnR 3 for (a) R= n-Bu, Y= H, p-OMe, o-Me, p- Me, m-Cl, p-Cl, m-CN, p-COCH 3 and m-NO 2, and (b) R= Me, Y= H, p-OMe, p-Me, p-CN, p- COCH 3, m-NO 2 and p-NO 2. Benzyl halides YC 6 H 4 CH 2 X (X= Cl or Br) similarly give ...

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