The Journal of Organic Chemistry

Reactions of allylsilanes with 4-substituted 1, 2, 4-triazoline-3, 5-diones

S Ohashi, WE Ruch, GB Butler

文献索引：Ohashi, Shinichi; Ruch, Wayne E.; Butler, George B. Journal of Organic Chemistry, 1981 , vol. 46, # 3 p. 614 - 619

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被引用次数: 26

摘要

The reaction between allyltrimethylsilane (1) and 4-phenyl-1, 2, 4-triazoline-3, 5-dione (2) was studied, and the structures of three products were determined by using'H NMR, 13C NMR, and mass spectra. The effects of solvent and temperature on the relative yields of products were studied, and a reaction mechanism involving an ionic intermediate was suggested. The mechanism of the reaction between diallyldimethylsilane (3) with ...