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The Journal of Organic Chemistry

3, 3'-Disubstituted 2, 2'-biphenols. Synthesis of nonplanar, tetradentate chelating ligands

TN Sorrell, DJ Ellis

文献索引:Sorrell, Thomas N.; Ellis, Debora J. Journal of Organic Chemistry, 1985 , vol. 50, # 26 p. 5765 - 5769

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被引用次数: 6

摘要

Our interest in preparing models for the active site of the molybdenum oxidases1 led us to consider the synthesis of new ligands that would bind to a metal ion, leaving two vacant cis- coordination sites. For Mo (V1) complexes, a flexible ligand would have been sufficient since most Mo (V1) systems have two cis MFO groups in their coordination spheres that dictate the overall geometry. 2