Bulletin of the Chemical Society of Japan

Kinetics and mechanism of oxidation of amino acids by dichloramine T.

BT Gowda, PJM Rao

文献索引：Gowda; Rao Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 10 p. 3303 - 3310

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被引用次数: 18

摘要

Kinetics of oxidations of several amino acids (alanine, leucine, aspargine, glutamine, and proline) by N, N-dichloro-p-toluenesulfonamide (generally known as dichloramine-T) have been studied in 1: 1 (v/v) water–methanol medium in the presence of perchloric acid. The oxidations of alanine and leucine showed second order kinetics in [oxidant], first order in [amino acid] and inverse fractional order in [H+] over the entire range of [HClO 4](0.0005– ...