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Metal catalysis in oxidation by peroxides. 24. Extraction of aqueous peroxomolybdenum species into organic media and their reactivity

O Bortolini, L Bragante, FD Furia…

文献索引:Bortolini, Olga; Bragante, Letanzio; Di Furia, Fulvio; Modena, Giorgio Canadian Journal of Chemistry, 1986 , vol. 64, p. 1189 - 1195

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被引用次数: 15

摘要

The effect of the lipophilicity and coordinating ability of neutral ligands, belonging to the classes of phosphoric amides and pyridine oxides, on the extraction of the neutral oxidants molybdenum (VI)-peroxo complexes from an aqueous acidic phase to an organic one, has been studied. The nature of the Mo (VI)-peroxo species present both in aqueous and organic phase has also been investigated. Sizable amounts of mineral acid, added to ...