Nucleophilic additions to thionolactones. New synthetic technology for the construction of medium and large ring ethers
KC Nicolaou, DG McGarry, PK Somers…
文献索引：Nicolaou, K. C.; McGarry, D. G.; Somers, P. K.; Veale, C. A.; Furst, G. T. Journal of the American Chemical Society, 1987 , vol. 109, # 8 p. 2504 - 2506
Medium-and large-ring molecular frameworks are abundant in nature'and are increasingly becoming targets for total synthesis. While a plethora of methods are now available for the synthesis of medium lactones and macrolactones, technology for the construction of the corresponding cyclic ethers is still emerging2 In this paper we report a new method for the construction of medium and large cyclic ethers from the readily available lactones3 via the ...
