Synthesis of 1, 2??Amino Alcohols by Sigmatropic Rearrangements of 3??(N??Tosylamino) allylic Alcohol Derivatives

M Barbazanges, C Meyer, J Cossy…

文献索引：Barbazanges, Marion; Meyer, Christophe; Cossy, Janine Organic Letters, 2008 , vol. 10, # 20 p. 4489 - 4492

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被引用次数: 22

摘要

Abstract Sigmatropic rearrangements of 3-(N-tosylamino) allylic alcohol derivatives, a particular subclass of functionalized enamides, have been investigated. Whereas the presence of the nitrogen atom alters the stereochemical outcome of Ireland–Claisen