Tetrahedron

Über galvinole und galvinoxyl-mehrspinsysteme—I: Eine neue metallorganische synthese von mono-und oligo-galvinolen

W Harrer, H Kurreck, J Reusch, W Gierke

文献索引：Harrer,W. et al. Tetrahedron, 1975 , vol. 31, p. 625 - 632

全文：HTML全文

被引用次数: 24

摘要

The synthesis of the so far unknown organometallic compound (2, 6-di-tert.-butyl-4- lithiumphenoxy)-trimethylsilane is most useful for the general introduction of the 3, 5-di-tert.- butyl-4-hydroxyphenyl group. Using the esters of aromatic mono-, di-, and tricarboxylic acids mono-, bis-, and tris-galvinoles are obtainable, while nitriles and dimethyl formamide are converted into ketones and the 3, 5-di-tert.-butyl-4-hydroxybenzaldehyde, respectively. In ...