Pentafluorosulfur carbonyl fluoride, pentafluorosulfur fluoroformate, and pentafluorosulfur peroxofluoroformate

R Czerepinski, GH Cady

文献索引：Czerepinski,R.; Cady,G.H. Journal of the American Chemical Society, 1968 , vol. 90, p. 3954 - 3959

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被引用次数: 20

摘要

Abstract: The compounds pentafluorosulfur carbonyl fluoride, SF, C (O) F, pentafluorosulfur fluoroformate, SFsOC (0) F, and pentafluorosulfur peroxofluoroformate, SFsOOC (0) F, are produced in low yields by ultraviolet irradiation of the following mixtures, respectively:(1) SzFlo and FC (O) C (O) F;(2) SFjOF and FC (O) C (O) F;(3) SF600SF6 with FC (O) OOC (O) F. Each of the new compounds reacts readily with a solution of sodium hydroxide and has ...