Chemistry Letters

A facile method for the oxidation of aldehydes to carboxylic acids via acetal-type diperoxides

T Mukaiyama, N Miyoshi, J Kato, M Ohshima

文献索引：Mukaiyama, Teruaki; Miyoshi, Norikazu; Kato, Jun-ichi; Ohshima, Masahiro Chemistry Letters, 1986 , p. 1385 - 1388

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被引用次数: 7

摘要

In the presence of a catalytic amount of trityl perchlorate, aldehydes smoothly react with t- butyl trimethylsilyl peroxide to give the acetal-type diperoxides in good yields. Treatment of these diperoxides with piperidine at 90° C or the aqueous solution of CUSO 4 and L- ascorbic acid at room temperature gave the corresponding carboxylic acids in good yields.