Chemical Communications

Perfluorovinyl–metal derivatives: a new one-pot synthesis

KK Banger, AK Brisdon, A Gupta

文献索引：Banger, Kulbinder K.; Brisdon, Alan K.; Gupta, Arti Chemical Communications, 1997 , # 1 p. 139 - 140

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被引用次数: 21

摘要

The one-pot reaction of the CFC replacement 1, 1, 1, 2-tetrafluoroethane (CF 3 CFH 2, HFC- 134a) with 2 equiv. of butyllithium in diethyl ether at-78° C followed by the addition of main- group or transition-metal halides results in good yields of the corresponding metal– perfluorovinyl compounds of high purity.