Addition reactions of lithiodimethylphenylsilane to (η 4-1, 3-diene)-Fe (CO) 3 and (η 6-arene) Cr (CO) 3 complexes

MCP Yeh, PY Sheu, JX Ho, YL Chiang, DY Chiu…

文献索引：Yeh, Ming-Chang P.; Sheu, Peng-Yu; Ho, Jin-Xuan; Chiang, Yi-Lin; Chiu, Dai-Yu; Narasimha Rao Journal of Organometallic Chemistry, 2003 , vol. 675, # 1-2 p. 13 - 20

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被引用次数: 1

摘要

Treatments of (η4-cyclohexa-1, 3-diene) Fe (CO) 3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1- dimethyl (phenyl) silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl (phenyl) silylcyclohexa-1, 3-diene] Fe (CO) 3 complex as the major product. Additions of the silyl anion to (η6-arene) Cr (CO) 3 and (η6-cyclohepta-1, 3, 5- ...