Canadian Journal of Chemistry

Nitration of 4-tert-butyl-o-xylene in acetic anhydride. Formation and rearomatization of adducts

A Fischer, KC Teo

文献索引：Fischer,A.; Teo,K.C. Canadian Journal of Chemistry, 1978 , vol. 56, p. 258 - 266

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被引用次数: 13

摘要

Nitration of 4-tert-butyl-1, 2-dimethylbenzene in acetic anhydride gives trans-1-tert-butyl-3, 4- dimethyl-4-nitro-1, 4-dihydrophenyl acetate (6), trans-1-tert-butyl-3, 4-dimethyl-4-nitro-1, 4- dihydrophenol, 2-tert-butyl-4, 5-dimethylphenyl acetate, 5-tert-butyl-2-methylbenzaldehyde, 4-tert-buty]-1, 2-dimethyl-5-nitrobenzene, and 4-tert-butyl-1, 2-dimethyl-6-nitrobenzene. 2- tert-Butyl-4, 5-dimethylphenyl acetate and 3, 4-dimethylphenyl acetate are the major ...