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Cross Alkyl–Aryl versus Homo Aryl–Aryl Coupling in Palladium-Catalyzed Coupling of Alkyl–Gold (I) and Aryl–Halide

…, MH Pérez-Temprano, JA Casares, P Espinet

文献索引:DelPozo, Juan; Casares, Juan A.; Espinet, Pablo Chemical Communications, 2013 , vol. 49, # 65 p. 7246 - 7248

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被引用次数: 5

摘要

Experiments on palladium-catalyzed cross-coupling of [AuMe (PPh3)] with aryl iodides show that Ar–Ar homocoupling products are the main product or an abundant byproduct of the reaction. The percentage of cross-coupling product is higher for aryls with a larger σp