A convenient route to diversely substituted icosahedral closomer nanoscaffolds

…, ZH Houston, MW Lee Jr, MF Hawthorne

文献索引：Jalisatgi, Satish S.; Kulkarni, Vikas S.; Tang, Betty; Houston, Zachary H.; Lee, Mark W.; Hawthorne, M. Frederick Journal of the American Chemical Society, 2011 , vol. 133, # 32 p. 12382 - 12385

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被引用次数: 17

摘要

The design and synthesis of icosahedral polyhedral borane closomer motifs based upon carbonate and carbamate anchoring groups for biomedical applications are described. Dodecacarbamate closomers containing easily accessible groups of interest at their linker termini were synthesized via activation of the B–OH vertices as aryl carbonates and their subsequent reaction with primary amines. Novel dodecacarbonate closomers were ...