Long??Lived Charge Separation in Novel Axial Donor–Porphyrin–Acceptor Triads Based on Tetrathiafulvalene, Aluminum (III) Porphyrin and Naphthalenediimide

…, AG Moiseev, R Gumbau??Brisa…

文献索引：Poddutoori, Prashanth K.; Zarrabi, Niloofar; Moiseev, Andrey G.; Gumbau-Brisa, Roger; Vassiliev, Serguei; Van Der Est, Art Chemistry - A European Journal, 2013 , vol. 19, # 9 p. 3148 - 3161

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被引用次数: 26

摘要

Abstract Two self-assembled supramolecular donor–acceptor triads consisting of Al III porphyrin (AlPor) with axially bound naphthalenediimide (NDI) as an acceptor and tetrathiafulvalene (TTF) as a secondary donor are reported. In the triads, the NDI and TTF units are attached to Al III on opposite faces of the porphyrin, through covalent and coordination bonds, respectively. Fluorescence studies show that the lowest excited ...