The Cyclic “Silver-Diphos” Motif [Ag2 (μ-diphosphine) 2] 2+ as a Synthon for Building up Larger Structures

…, M Nieuwenhuyzen, JPH Charmant, SL James

文献索引：Miller, Philip W.; Nieuwenhuyzen, Mark; Charmant, Jonathan P. H.; James, Stuart L. Inorganic Chemistry, 2008 , vol. 47, # 18 p. 8367 - 8379

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被引用次数: 22

摘要

The cyclic silver-diphos motif has been investigated as a synthon for building up complex structures. Reactions between silver ions and di-, tetra-, hexa-, hepta-, or octaphosphines gives a series of dimers and cages as well as an unusual tetra-chelate complex. If the diphosphine groups are sufficiently well-separated, the “silver-diphos” motif is found to be a promising synthon for rational self-assembly.