Chemistry–A European Journal

Radical??Mediated Diamination of Alkenes with Phenylhydrazine and Azodicarboxylates: Highly Diastereoselective Synthesis of trans??Diamines from Cycloalkenes

MK Zhu, YC Chen, TP Loh

文献索引：Zhu, Ming-Kui; Chen, Yu-Chen; Loh, Teck-Peng Chemistry - A European Journal, 2013 , vol. 19, # 17 p. 5250 - 5254

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被引用次数: 24

摘要

Vicinal diamines represent a very important class of compounds in organic chemistry as they not only serve as lig-ACHTUNGTRENNUNGands or catalysts in asymmetric reactions, but have also been shown to exhibit a broad spectrum of biological activities.[1] Among the many methods, direct diamination of simple unsaturated hydrocarbons offers one of the most straightforward and practical approaches to this motif. Although significant progress has ...