The reaction of acetic acid 2??selenoxo??2H??pyridin??1??yl esters with benzynes: A convenient route to Benzo [b] seleno [2, 3??b] pyridines

U Narasimha Rao, R Sathunuru…

文献索引：Rao, U. Narasimha; Sathunuru, Ramadas; Maguire, John A.; Biehl, Ed Journal of Heterocyclic Chemistry, 2004 , vol. 41, # 1 p. 13 - 21

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被引用次数: 12

摘要

Abstract Benzyne and its 3, 4, 5, 6-tetraphenyl, 3-and 4-methyl, 3-methoxy and 4, 5-difluoro derivatives react with acetic acid 2-selenoxo-2H-pyridin-1-yl esters 4a-e to give benzo [b] seleno [2, 3-b] pyridines 10–15 in modest yields. The benzynes were generated by one or more of the following methods: diazotization of anthranilic acids 5a-g with isoamyl nitrate; mild thermal decomposition of 2-diazoniobenzenecarboxylate hydrochlorides 6a-d ...