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Palladium Catalyzed, Regioselective Reduction of 1, 2-Epoxides by Ammonium Formate

PS Dragovich, TJ Prins, R Zhou

文献索引:Dragovich, Peter S.; Prins, Thomas, J.; Zhou, Ru Journal of Organic Chemistry, 1995 , vol. 60, # 15 p. 4922 - 4924

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被引用次数: 38

摘要

The reduction of an epoxide to a saturated alcohol is a useful transformation in organic synthesis, and many methods have been developed which accomplish this conversion. l Of these, catalytic hydrogenolysis ranks among the simplest and has been utilized extensively in the past for the reduction of a variety of oxirane sub-More recently, several reagent combinations have been discovered which effect catalytic hydrogenolysis under mild ...