Sulfonium salts. Participants par excellence in metal-catalyzed carbon-carbon bond-forming reactions

J Srogl, GD Allred, LS Liebeskind

文献索引：Srogl, Jiri; Allred, Gary D.; Liebeskind, Lanny S. Journal of the American Chemical Society, 1997 , vol. 119, # 50 p. 12376 - 12377

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被引用次数: 155

摘要

During the past decade, novel biological roles have been identified for metalloenzyme- induced transformations at the carbon-sulfur bond of biomolecules. Since metal-mediated rupture of a carbon-sulfur bond is a key step in a number of these processes, 1-3 new and synthetically useful transformations of organosulfur compounds mediated by metals might be discovered by following nature's example. 4 Consider, for example, the sulfonium salt. ...