Reaction of Grignard Compounds with 4-Chloro-2-methyl-3-butyn-2-ol in Diethyl Ether Equivalents

SA Shchelkunov, OA Sivolobova, SO Mataeva…

文献索引：Shchelkunov; Sivolobova; Mataeva; Minbaev; Muldakhmetov Russian Journal of Organic Chemistry, 2001 , vol. 37, # 1 p. 5 - 8

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被引用次数: 1

摘要

Abstract Reactions of RMgX· THF complexes with 4-chloro-2-methyl-3-butyn-2-ol in aromatic hydrocarbons were studied. The complexes formed by arylmagnesium halides require the presence of anisole for the reaction to occur. 4-Chloro-2-methyl-3-butyn-2-ol can be synthesized by reaction of 2-methyl-3-butyn-2-ol with sodium hypochloride in the two-phase system water-benzene.