The Addition of the Trichloromethyl Radical to ω-Phenylalkenes

MM Martin, GJ Gleicher

文献索引：Martin,M.M.; Gleicher,G.J. Journal of the American Chemical Society, 1964 , vol. 86, p. 238 - 241

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被引用次数: 20

摘要

It has been found that the reactivity of the double bond in the series CBHs (CH,~), CH= CH2 and CcHs (CHd,,-CH= C (CH1)? toward addition hg the trichloromethyl radical reaches a maximum when n= 2 and decreases as n increases. This dependence of reactivity on chain length is interpreted in terins of a Inechanisnl in which the trichlorornethyl radical first complexes with the benzene ring of the phenylalkene, followed by an addition step in ...