Synthesis and crystal structure of disiloxane-1, 3-diols and disiloxane-1, 1, 3, 3-tetraol

K Suyama, T Nakatsuka, T Gunji, Y Abe

文献索引：Suyama, Ken-ichi; Nakatsuka, Takanori; Gunji, Takahiro; Abe, Yoshimoto Journal of Organometallic Chemistry, 2007 , vol. 692, # 10 p. 2028 - 2035

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被引用次数: 5

摘要

1, 3-Dimethyl-or 1, 3-divinyl-1, 3-di-t-butoxydisiloxane-1, 3-diol and 1, 3-diphenyldisiloxane- 1, 1, 3, 3-tetraol were synthesized by hydrolysis of the corresponding diisocyanatodisiloxanes and tetrachlorodisiloxane. The disiloxanediols were soluble in common organic solvents and thermally very stable, therefore, they could be sublimed without decomposition. X-ray crystallography showed that the disiloxane-1, 3-diols in the ...