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Preparation and ESR studies of new stable tocopheroxyl model radicals

K Mukai, K Takamatsu, K Ishizu

文献索引:Mukai, Kazuo; Takamatsu, Kimiko; Ishizu, Kazuhiko Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 12 p. 3507 - 3510

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被引用次数: 25

摘要

New tocopherol (vitamin E) model compounds (tocopherol 1; 7-t-butyl-2, 2-dimethyl-6- chromanol, tocopherol 2; 7-t-butyl-2, 2, 5-trimethyl-6-chromanol, and tocopherol 3; 5, 7- diisopropyl-2, 2-dimethyl-6-chromanol) have been synthesized by condensation of 2-methyl- 3-buten-2-ol to the corresponding alkylhydroquinone. Electron spin resonance measurements were performed for the tocopheroxyl radicals obtained from the above ...