Synthesis of Group IV (Zr, Hf)− Group VIII (Fe, Ru) Heterobimetallic Complexes Bearing Metallocenyl Diphosphine Moieties and Their Application to Catalytic …

…, Y Tanabe, M Yuki, Y Miyake, Y Nishibayashi

文献索引：Tanaka, Hiromasa; Sasada, Akira; Kouno, Tomohisa; Yuki, Masahiro; Miyake, Yoshihiro; Nakanishi, Haruyuki; Nishibayashi, Yoshiaki; Yoshizawa, Kazunari Journal of the American Chemical Society, 2011 , vol. 133, # 10 p. 3498 - 3506

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被引用次数: 30

摘要

A series of heterobimetallic complexes, including [M1Me (μ-η5: η1-C5H4PEt2) 2M2Cp*](5a, M1= Zr, M2= Ru; 5b, M1= Hf, M2= Ru; 5c, M1= Zr, M2= Fe) have been prepared and characterized by X-ray analyses. Dehydrogenation of Me2NH· BH3 takes place in the presence of a catalytic amount of these heterobimetallic complexes. Studies on the reaction pathway of the catalytic dehydrogenation of Me2NH· BH3 lead us to propose a catalytic ...